AR-C260P (serv.man42). MSDS (F-01191) for AR-C26TBE (Black Toner) - Sharp Copying Equipment Regulatory Data (repair manual). Page 3

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MATERIAL  SAFETY  DATA  SHEET  
 
Date Revised : Jul.  1. 2004 
Date Issued   :Oct.    1.2002 
MSDS:F-01191  
 
8. EXPOSURE CONTROLS/PERSONAL PROTECTION 
Engineering Measures   Ventilation : Not required under intended use. 
Exposure limit values  
OSHA-PEL(USA) 
: 15mg/m
3
 (Total Dust) 
, 5mg/m
3
 (Respirable Dust) 
ACGIH-TLV(USA) 
: 10mg/m
3
 (Total Dust) 
, 3mg/m
3
 (Respirable Dust)        
OHSC-TWA(Australia)                  :10mg/m
3
 (Total Dust)
 
Personal Protective Equipment  
Respiratory Protection 
:  None required when used as intended in Sharp equipment. 
Hand Protection 
:  None required when used as intended in Sharp equipment. 
Eye Protection 
:  None required when used as intended in Sharp equipment. 
Skin Protection 
:  None required when used as intended in Sharp equipment. 
Other Protective Equipment   :  Use of a dust mask and goggles are recommended when handling a large quantity of 
toner or during long term exposure, as with any non-toxic dust.
   
 
9.  PHYSICAL AND CHEMICAL PROPERTIES 
Appearance     Physical State : Solid  
Form: Powder                Color: Black 
Odor: odorless 
Ph : Not applicable 
Boiling/Melting Point 
: Not applicable 
Softening Point(°C ) 
: 100 - 130 
Flash Point(°C ) 
Not applicable 
lgnition Point(°C ) 
: No data 
Explosion Properties 
: No data  
Density(g/cm³) : Approx. 1.1  (bulk density : Approx. 0.4) 
Solubility in water 
: Negligible 
10. STABILITY AND REACTIVITY 
Stability : Stable  
Hazardous Reactions 
: Dust explosion, like most finely divided organic powders. 
Conditions to Avoid 
: Electric discharge, throwing into fire. 
Materials to Avoid 
: Oxidizing Materials 
Hazardous Decomposition Products : CO, CO
2
 and NO
X
 
Further Information 
: None
 
11. TOXICOLOGICAL INFORMATION 
Acute Toxicity  
 Ingestion(oral) 
: LD
50
>2500mg/kg         [Estimated from the other product containing similar material] 
Dermal                   : LD
50
>2500mg/kg         [Estimated from Acute oral toxicity for the same product] 
 Inhalation 
: LC
50
>5.00mg/l  (Rats, 4hr) 
 
 Eye 
irritation : Not an irritant              [Estimated from the other product containing similar material] 
 Skin 
irritation : Not an irritant              [Estimated from the other product containing similar material] 
 Skin 
sensitizer 
: Not sensitized             [Estimated from the other product containing similar material] 
Mutagenicity : Negative(Ames Test)  [Estimated from the other product containing similar material] 
Carcinogenicity : In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human 
carcinogen).  This classification is given to chemicals for which there is inadequate human 
evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity.  The 
classification is based upon the development of lung tumors in rats receiving chronic inhalation 
exposures to free carbon black at levels that induce particle overload of the lung.  Studies 
performed in animal models other than rats did not show any association between carbon black 
and lung tumors.  Moreover, a two-year cancer bioassay using a typical toner preparation , 
where carbon black is bound in a resin matrix, demonstrated no association between toner 
exposure and tumor development in rats. 
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